ALUMINIUM SULFATE

it can act as an Coagulant, Flocculant, Precipitant and Emulsion Breaker. As coagulant and flocculant, aluminum sulfate successfully removes turbidity, suspended solids and colloidal color,reduces biochemical oxygen demand (BOD) and extremely clarifi

Aluminium Sulphate for water treatment. Its wide range of usage is in water treatment, because it can act as an coagulant, flocculant, precipitant and emulsion breaker. As coagulant and flocculant, aluminum sulfate successfully removes turbidity, suspended solids and colloidal color,reduces biochemical oxygen demand (BOD) and extremely clarifies potable, process and wastewaters.

Application

Also used as foam fire extinguisher 

Aluminium sulfate reacts with sodium bicarbonate to which foam stabilizer has been added, producing carbon dioxide for fire extinguishing foam. 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

  • Al2(SO4)3 + 6 NaHCO3 → 3 Na2SO4 + 2 Al(OH)3 + 6 CO2

    The carbon dioxide is trapped by the foam stabilizer and creates a thick foam which will float on top of hydrocarbon fuels and seal off access to atmospheric oxygen, smothering the fire. Chemical foam was unsuitable for use on polar solvents such as alcohol, as the fuel would mix with and break down the foam blanket. The carbon dioxide generated also served to propel the foam out of the container, be it a portable fire extinguisher or fixed installation using hoselines. Chemical foam is considered obsolete in the United States and has been replaced by synthetic mechanical foams, such as AFFF which have a longer shelf life, are more effective, and more versatile, although some countries such as Japan and India continue to use it.

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    In the construction industry, it is used as waterproofing agent and accelerator in concrete.

    Dose

    - For the production of Aluminum salts, Soaps and Aluminum Hydroxide Gel. - As a Catalyst in Ethane Production.
    - Textile industry.
    - Paper production. 

    - For the production of Glycerin
    - As a Foaming Agent in Fiber Foams.
    - As a Clearing Agent for Fats and Foams. - In sugar industry. 

    Technical specifications
     

    Item

    Index

    Aluminum Sulfate

    15.8%

    17%

    A12O3 % ≥

    15.8

    17

    Iron Fe content % ≤

    0.50

    0.005

    Water insoluble matter % ≤

    0.15

    0.15

    PH value 1% aqueous solution ≥

    3.0

    3.0

    Heavy metals as Pb % ≤

    0.002

    0.002

    AS % ≤

    0.0005

    0.0005

    Granularity ≥

    -----

    15

     

    Item

    Index

    Aluminum Sulfate

    15.8%

    17%

    A12O3 % ≥

    15.8

    17

    Iron Fe content % ≤

    0.50

    0.005

    Water insoluble matter % ≤

    0.15

    0.15

    PH value 1% aqueous solution ≥

    3.0

    3.0

    Heavy metals as Pb % ≤

    0.002

    0.002

    AS % ≤

    0.0005

    0.0005

    Granularity ≥

    -----

    15

     

    Item

    Index

    Aluminum Sulfate

    15.8%

    17%

    A12O3 % ≥

    15.8

    17

    Iron Fe content % ≤

    0.50

    0.005

    Water insoluble matter % ≤

    0.15

    0.15

    PH value 1% aqueous solution ≥

    3.0

    3.0

    Heavy metals as Pb % ≤

    0.002

    0.002

    AS % ≤

    0.0005

    0.0005

    Granularity ≥

    -----

    15

     

    Note

    properties :::---

    1. Properties: Including anhydrous and hydrous(18 crystal water) type. Usually, the crystal separated out from aqueous solution at the normal temperature is A12(SO4) 3.18H2O; When weathering, the average molecular structure is A12(SO4) 3.14H2O, may appear white powdery, with bright flake or crystalline flakelet, odorless, to change the taste from sweetness to slight astringency.

    2. Uses: Solidifying agent ( to purify grease and water ) and stabilizer in pasteurization of albumin ( including: liquid or refrigerated whole egg, egg white or egg yolk ), the maximum allowable use level ( FAO/WHO.1984 ) is 0.036%.

    3. Standard: HG2225-2001

    4. State: Flake or powder

    5. Packing: 25/50 kg/bag, 25MT/20'FCL

    Remarks / Precaution

    ALUMINIUM SULFATE Al2(SO4)3

    Packing sizes
    20 Kg Slab Manufacturer & Exporters of Non Ferric Alum Slab in India.
    MSDS

    Product Name               ALUMINIUM SULFATE
    Part Number   RXSOL-19-1904-025

    Company Details:

    RX MARINE INTERNATIONAL
    105, A wing , BSEL , TECH PARK.
    VASHI ,NEW BOMBAY 400703 INDIA

    Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

    Phone +91 22 20871200 - 1400
    Fax +91 22 27612100 :::AOH :0091 9821214367
    Email mail@rxmarine.com
    Website www.rxmraine.com

    Substances

    Formula Al2O12S3
    Molecular weight  342,15 g/mol
    CAS-No. 10043-01-3
    EC-No. 233-135-0
    Component Classification Concentration
    Aluminium sulfate    
    CAS-No.                10043-01-3
    EC-No.                   233-135-0
    Met. Corr. 1; Eye Dam. 1;
    H290, H318
    = 100 %

    Classification of the substance or mixture

    Classification according to Regulation (EC) No 1272/2008
    Corrosive to Metals (Category 1), H290
    Serious eye damage (Category 1), H318
    For the full text of the H-Statements mentioned in this Section, see Section 16.

    Label elements

    Signal Word Danger
    Hazard statement(s)
    H290 May be corrosive to metals.
    H318 Causes serious eye damage.
    Precautionary statement(s)
    P234 Keep only in original packaging.
    P280 Wear eye protection/ face protection.
    P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
    Remove contact lenses, if present and easy to do. Continue rinsing.
    P390 Absorb spillage to prevent material damage.
    Supplemental Hazard Statements None
    Signal Word Danger
    Hazard statement(s) H318 Causes serious eye damage.
    Precautionary statement(s)
    P280 Wear eye protection/ face protection.
    P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
    Remove contact lenses, if present and easy to do. Continue rinsing.
    Supplemental Hazard Statements None
    Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

    General Advice Show this material safety data sheet to the doctor in attendance.
    If inhaled After inhalation: fresh air.
    In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.
    In case of eye contact After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
    If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
    Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 
    Indication of any immediate medical attention and special treatment needed No data available

    Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
    Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given.
    Special hazards arising from the substance or mixture
    Sulfur oxides
    Aluminum oxide
    Not combustible.
    Ambient fire may liberate hazardous vapours.
    Advice for firefighters In the event of fire, wear self-contained breathing apparatus.
    Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

    Personal precautions, protective equipment and emergency procedures
    Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.
    For personal protection see section 8.
    Environmental precautions Do not let product enter drains.
    Methods and material for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area.
    Reference to other sections For disposal see section 13.

    Precautions for safe handling For precautions see section 2.2.
    Storage conditions
    No metal containers.
    Tightly closed. Dry.
    hygroscopic Store under inert gas.
    Storage class Storage class (TRGS 510): 8B: Non-combustible, corrosive hazardous materials
    Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

    Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
    Body Protection
    Protective clothing
    Respiratory protection
    Required when dusts are generated.
    Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
    Recommended Filter type: Filter type P2
    The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
    These measures have to be properly documented.
    Control of environmental exposure Do not let product enter drains.

    Physical state Powder
    Color White
    Odor Odorless
    Melting point/freezing point Melting point/range: 770 °C - dec.
    Initial boiling point and boiling range 112 - 116 °C
    Flammability (solid, gas) The product is not flammable. - Flammability (solids)
    Upper/lower flammability or explosive limits
    No data available
    Flash point No data available
    Autoignition temperature No data available
    Decomposition temperature No data available
    pH No data available
    Viscosity
    Viscosity, kinematic: No data available
    Viscosity, dynamic: No data available
    Water solubility
    ca.0,00001 g/l at 21,5 °C - insoluble
    Partition coefficient: n-octanol/water Not applicable for inorganic substances
    Vapor pressure No data available
    Density 2,71 g/mL at 25 °C - lit.
    Relative density No data available
    Relative vapor density No data available
    Particle characteristics No data available
    Explosive properties No data available
    Oxidizing properties None
    Other safety information No data available

    Reactivity        
    No data available
    Chemical stability The product is chemically stable under standard ambient conditions (room temperature)
    Possibility of hazardous reactions No data available
    Conditions to avoid
    Air Exposure to moisture.
    No information available
    Incompatible materials No data available
    Hazardous decomposition products In the event of fire: see section 5

    Acute toxicity
    LD50 Oral - Rat - male and female - > 2.000 mg/kg
    (OECD Test Guideline 401)
    Inhalation: No data available
    LD50 Dermal - Rabbit - male and female - > 5.000 mg/kg
    (OECD Test Guideline 402)
    Skin corrosion/irritation
    Skin - Rabbit
    Result: No skin irritation - 4 h
    (OECD Test Guideline 404)
    Serious eye damage/eye irritation
    Eyes - Rabbit
    Result: Irreversible effects on the eye
    (OECD Test Guideline 405)
    Respiratory or skin sensitization
    Local lymph node assay (LLNA) - Mouse
    Result: negative
    (OECD Test Guideline 429)
    Germ cell mutagenicity
    Test Type: Ames test
    Test system: Escherichia coli/Salmonella typhimurium
    Metabolic activation: with and without metabolic activation
    Method: OECD Test Guideline 471
    Result: negative
    Test Type: In vitro mammalian cell gene mutation test
    Test system: mouse lymphoma cells
    Metabolic activation: with and without metabolic activation
    Method: OECD Test Guideline 476
    Result: negative
    Test Type: Micronucleus test
    Test system: Human lymphocytes
    Metabolic activation: with and without metabolic activation
    Method: OECD Test Guideline 487
    Result: negative
    Test Type: Micronucleus test
    Species: Rat
    Application Route: Oral
    Method: OECD Test Guideline 474
    Result: negative
    Remarks: (in analogy to similar products)
    The value is given in analogy to the following substances: aluminium hydroxide
    Species: Rat
    Application Route: Oral
    Remarks: Cytogenetic analysis
    Carcinogenicity No data available
    Reproductive toxicity 
    No data available
    Specific target organ toxicity - single exposure No data available
    Specific target organ toxicity - repeated exposure No data available
    Aspiration hazard No data available
    Additional Information
    Endocrine disrupting properties
     
    Toxicity  
    Toxicity to fish
    Semi-static test LC50 - Danio rerio (zebra fish) - > 87,5 mg/l - 96 h
    (OECD Test Guideline 203)
    Toxicity to daphnia and other aquatic invertebrates
    Static test EC50 - Daphnia magna (Water flea) - > 200 mg/l - 48 h
    (OECD Test Guideline 202)
    Toxicity to algae
    Static test ErC50 - Pseudokirchneriella subcapitata (microalgae) -
    0,24 mg/l - 72 h
    (OECD Test Guideline 201)
    Toxicity to bacteria
    Static test EC50 - activated sludge - > 200 mg/l - 3 h
    (OECD Test Guideline 209)
    Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.
    Bioaccumulative potential No data available
    Mobility in soil No data available
    Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
    Endocrine disrupting properties
    Product
     
    Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
    Other adverse effects No data available

    Waste Treatment Methods No data available

    UN number ADR/RID:  3260         IMDG:   3260      IATA: 3260
    UN proper shipping name
    ADR/RID: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (aluminium sulfate)
    IMDG: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (aluminium sulfate)
    IATA: Corrosive solid, acidic, inorganic, n.o.s. (aluminium sulfate)
    Transport hazard class(es) ADR/RID:  8    IMDG:  8     IATA: 8
    Packaging group ADR/RID:     lll             IMDG:    lll               IATA: lll
    Environmental hazards ADR/RID: No               IMDG Marine pollutant: No          IATA: No
    Special precautions for user  
    Tunnel restriction code (E)
    Further information No data available

    Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
    Other regulations Take note of Dir 94/33/EC on the protection of young people at work.
    Chemical Safety Assessment For this product a chemical safety assessment was not carried out
     
    Other Information

    The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchant ability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own nvestigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, how so ever arising, even if Rx Marine International  has been advised of the possibility of such damages.

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