Crystals or granules are dark purple with a metallic sheen, sometimes with a dark bronze-like appearance. Free-Flowing Grade is gray due to an additive. Potassium permanganate has a sweetish, astringent taste and is odorless.
Potassium Permagnate Also known as KMnO4, Condy’s Crystals and permanganate of potash. Its frequent uses is for various field like Purifying water, Creating an antiseptic solution, As an anti-fungal treatment for the hands and feet, As a cholera disinfectant, General disinfectant agent.
Potassium permanganate is used extensively in the water treatment industry. It is used as a regeneration chemical to remove iron and hydrogen sulfide (rotten egg smell) from well water via a "Manganese Greensand" Filter. "Pot-Perm" is also obtainable at pool supply stores and is used additionally to treat waste water. Historically it was used to disinfect drinking water.It currently finds application in the control of nuisance organisms such as Zebra mussels in fresh water collection and treatment systems.
Almost all applications of potassium permanganate exploit its oxidizing properties. As a strong oxidant that does not generate toxic byproducts, KMnO4 has many niche uses. One of the uses can be said to be as a fixative. This list is by no means the only applications that Potassium Permanganate is used for, but it covers some of the more common applications. The optimum condition under which it is to be used can be easily established through technical service evaluations or laboratory testing.
Water Treatment - Oxidizes iron, manganese, and hydrogensulfide; controls taste and odor; and is an alternate pre-oxidant for Disinfection By-Product (THMs and HAAs) control. Variety of disease causing organisms including bacteria, yeast, fungus, spores, and viruses growing in water. Drinking Water disinfectant can also be done by other common process process is to add 1-pound of calcium hypochlorite in granular form in to 10,000 gallons of drinking water. And Calcium Hypochlorite is widely available for use as swimming pool chlorine tablets or white powder that is much more stable than chlorine. And we have H2S vial (Bacteriological ) Kit use for checking microbiological quality of water. Water borne diseases like typhoid ,cholera, diarrhoea and jaundice and caused by polluted water supply.
Municipal Wastewater Treatment - Destroys hydrogen sulfide in wastewater and sludge. Improves sludge dewatering. Industrial Wastewater Treatment - Oxidizes hydrogen sulfide, phenols, iron, manganese, and many other organic and inorganic contaminants; resultant manganese dioxide aids in removing heavy metals.
Metal Surface Treatment - Conditions mill scale and smut to facilitate subsequent removal by acid pickling in wrought metals manufacturing and jet engine cleaning. Purification of Gases - Removes trace impurities of sulfur, arsine, phosphine, silane, borane, and sulfides from carbon dioxide and other industrial gases.
Mining and Metallurgical - Aids in separation of molybdenum from copper; removes impurities from zinc and cadmium; oxidizes flotation compounds. Removes iron and manganese from acid mine drainage.
Chemical manufacture and processing: Aids in synthesis of organic products for the chemical process and pharmaceutical industries.
Aquaculture (fish farming): Controls fish diseases and parasites, and detoxifies poisons while relieving oxygen depletion in fish ponds.
Air and gas purification: Removes pollutants from air and impurities from industrial gases, and quenches slag from foundry operations.
Fumigation of Poultry farms, Hatcheries, Mushroom farms, other culture environment and Operation theatres in Hospitals.
Its Dose Depends according to application.
TYPICAL and Common use :
Ethylene absorbents extend storage time of bananas even at high temperatures. This effect can be exploited by packing bananas in polyethylene together with potassium permanganate. By removing ethylene by oxidation, the permanganate delays the ripening, increasing the fruit's shelf life up to 4 weeks without the need for refrigeration.
USEFUL LINK to test Bacterial / germs growth in drinking water... http://www.rxmarine.com/H2S-vial-Bacteriological-Kit-manufacturer-supplier-test-kit
| Odour | : | Odourless |
| Taste | : | Sweetish, astringent. |
| Appereance | : | Solid/Powder/Crystal |
| Molecular Weight | : | 158.03 g/mole |
| pH (1% soln/water) | : | Not available |
| Boiling Point | : | Not available |
| Melting Point | : | Decomposes. |
| Critical Temperature | : | Not available. |
| Specific Gravity | : | 2.7 @ 15 C (Water = 1) |
| Solubility | : |
Easily soluble in methanol, acetone. Partially soluble in cold water, hot water. Soluble in Sulfuric Acid. |
Drinking Water treatment with Potassium Permagnate ::: http://www.dubichem.com/Drinking-Water-treatment-with-Potassium-Permagnate
COMPATIBILITY INFORMATION
RXSOL™ potassium permanganate is compatible with many metals and synthetic materials. Natural rubbers and fibers are often incompatible. Solution pH and temperature are also important factors. The material must be compatible with either the acid or alkali also being used.
In neutral and alkaline solutions, RXSOL™ potassium permanganate is not corrosive to iron, mild steel, or stainless steel; however, chloride corrosion of metals may be accelerated when an oxidant such as RXSOL™ potassium permanganate is present in solution. Plastics such as polypropylene, polyvinyl chloride Type I (PVC I), epoxy resins, fiberglass reinforced plastic (FRP), Penton, Lucite, Viton A, and Hypalon are suitable. Teflon FEP and TFE, and Tefzel ETFE are best. Refer to Material Compatibility Chart.
Aluminum, zinc, copper, lead, and alloys containing these metals may be (slightly) affected by RXSOL™ potassium permanganate solutions. Actual studies should be made under the conditions in which the product will be used.
HANDLING AND STORAGE
Protect containers against physical damage. When handling potassium permanganate, respirators should be worn to avoid irritation of or damage to mucous membranes. Eye protection should also be worn when handling potassium permanganate as a solid or in solution. Potassium permanganate is stable and will keep indefinitely if stored in a cool, dry area in closed containers. Concrete floors are preferred to wooden decks. To clean up spills and leaks, follow the steps recommended in the MSDS. Be sure to use goggles, rubber gloves, and respirator when cleaning up a spill or leak.
Avoid contact with acids, peroxides, and all combustible organic or readily oxidizable materials including inorganic oxidizable materials and metal powders. With hydrochloric acid, chlorine gas is liberated. Potassium permanganate is not combustible, but will support combustion. It may decompose if exposed to intense heat. Fires may be controlled and extinguished by using large quantities of water. Refer to the MSDS for more information.
SHIPPING & PACKING : 5 Kgs, 1o Kgs, 25 Kgs, 50 Kgs Plastic Container
Proceed with caution, however. The information provided in this article is intended for emergency situations only. Caution should be exercised when using any of the following information.
Potassium permanganate will start a fire when mixed with a couple of different compounds. Glycerin is the most common, but antifreeze will also do the trick. Antifreeze seems to create a reaction that is a little more violent. Be very careful when using either. The reaction is not always immediate. It can take several seconds for the reaction to start a fire – let it be.
After gathering all the necessary fire tinder and large pieces of wood to keep your fire going, place a teaspoon of Potassium permanganate on a flat surface. Carefully add the same amount of Glycerine or Antifreeze evenly on top of your pile. Next, stand back a couple of feet and wait at the ready with your tinder.
Mix sugar in with the Glycerin before adding to your Condy’s Crystals, and you’ll get a decent signal smoke.
For water purification, its use is relatively straight forward. First, if there is any sediment in the water, strain it out. Then add 3 – 4 crystals per liter of water. Stir or shake for a few seconds then let sit for 2 hours. The water should be a light pink (a concentration of 1:10,000) – no darker.
Here are some proportions for killing the different nasty organisms that can find their way into water:
Bacteria requires a minimum of 2.5mg per liter of water.
Viruses require a minimum of 50mg (close to danger levels) per liter.
Potassium permanganate can become toxic in high concentrations, just like anything. The lowest recorded instance of a person poisoned was 100mg per kilogram of body weight. That said, the LD50 scale for Potassium permanganate is 1900mg per kilogram of body weight.
Just remember, as long as it is pink – it’s probably ok to drink.
To use as an antiseptic, anti-fungal treatment, or emergency snow signal, add crystals one by one until the solution turns purple. Shake and use to flush out a wound, soak a fungal infection, or to leave a message in the snow.
Don’t eat snow marked in yellow – just saying.
Ideally, Potassium permanganate should be stored in a nonreactive plastic bottle with a Teflon coated cap. Most plastic bottles and non-coated caps should be fine.
Potassium permanganate is not a perfect option for any of the above-listed purposes. If other more convention options are available – use them first. What it does do is offer another option should you find yourself with it as your only resource.
| Product Name | Potassium Permanganate |
| Part Number | RXSOL-60-6109-025 |
Chemical Formula: KMnO4
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Kolkata, Chennai, Visakhapatnam, Gandhidham, Nairobi
| Phone | +91 22 65113333/ 5555 / 9999 / 27815540-42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| mail@rxmarine.com; 123@rxmarine.com |
|
Chemical Name |
Concentration |
CAS Number |
EC Number |
R Phrases* |
Symbols |
|
Potassium Permanganate |
99-100% |
7722-64-7 |
231-760-3 |
50/5 |
Xn |
*See Section 16
|
Physical hazards |
Not Classified |
|
Health hazards |
Not Classified |
|
Environmental Hazards |
Aquatic Chronic 2 - H411 |
|
Potential Acute Health Effects |
Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator). Possibly corrosive to eyes and skin. The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. |
|
Potential Chronic Health Effects |
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, skin, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local |
|
Contact with skin |
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. |
|
Contact with eyes |
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. |
|
Ingestion |
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband |
|
Inhalation |
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. |
|
General |
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. |
| Flammability of the Product | : | Non-flammable |
| Auto-Ignition Temperature | : | Not applicable. |
| Flash Points | : | Not applicable. |
| Flammable Limits | : | Not applicable. |
| Products of Combustion | : | Not applicable. |
| Fire Hazards in Presence of Various Substances | : | organic materials, metals, combustible materials |
| Explosion Hazards in Presence of Various Substances | : | Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Explosive in presence of organic materials, of metals. |
| Fire Fighting Media and Instructions | : |
Not applicable. |
| Special Remarks on Fire Hazards | : | Spontaneously flammable on contact with ethylene glycol. Potassium Permanganate being conveyed through propylene tube ignited the tube. When solid hydroxylamine is brought into contact with solid potassium permanganate, there is produced immediately a with flame. Potassium permanganate decomposes hydrogen trisulfide so rapidly that sufficient heat is liberated to ignite the trisulfide. When Antimony or arsenic and solid potassium permanganate are ground together, the metals ignite. |
| Special Remarks on Explosion Hazards | ; | Take care in handling as explosions may occur if it is brought in contact with organic or other readily oxidizable substances, either in solution or in dry state. Explosive in contact with sulfuric acid or hydrogen peroxide. Potassium permanganate + acetic acid or acetic anhydride can explode if permanganate is not kept cold. Explosions can occur when permanganates come on contact with benzene, carbon disulfide, diethyl ether, ethyl alcohol, petroleum, or oganic matter. Contact with glycero may produce explosion. Crystals of potassium permanganate explode vigorously when ground with phosphorous. A mixture of .5% potassium permanganate + ammonium nitrate explosive caused an explosion 7 hrs. later. Addition of Potassium permanganate + dimethylformamide to give a 20% solution led to an explosion after 5 min. During a preparation of chlorine by addition of the concentrated acid (Hydrochloric acid) to solid potassium permanganate, a sharp explosion occurred on one occasion. |
|
Personal Precautions |
Wear protective clothing as per section 8. |
|
Environmental Precautions |
Avoid discharge into drains or watercourses or onto the ground. Contain spillage with sand,earth or other suitable non-combustible material. The product contains substances which are water-soluble and may spread in water systems. The product contains volatile substances which may spread in the atmosphere |
|
Immediate Actions |
Shut off source of leak if safe to do so. |
|
Small Spill |
Use appropriate tools to put the spilled solid in a convenient waste disposal container. |
|
Large Spill |
Oxidizing material. Corrosive solid. Stop leak if without risk. Do not get water inside container. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. |
|
Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material. Do not ingest. Do not breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as organic materials, metals, acids. |
|
Storage |
Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers. |
|
Engineering Control |
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
|
Personal Protection |
Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. |
|
Personal Protection in case of Large Spill |
Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. |
|
Exposure Limits |
TWA: 5 Consult local authorities for acceptable exposure limits. |
| Odour | : | Odourless |
| Taste | : | Sweetish, astringent. |
| Appereance | : | Solid/Powder/Crystal |
| Molecular Weight | : | 158.03 g/mole |
| pH (1% soln/water) | : | Not available |
| Boiling Point | : | Not available |
| Melting Point | : | Decomposes. |
| Critical Temperature | : | Not available. |
| Specific Gravity | : | 2.7 @ 15 C (Water = 1) |
| Vapor Pressure | : | Not available. |
| Vapor Density | : | Not available. |
| Volatility | : | Not available. |
| Odor Threshold | : | Not available. |
| Water/Oil Coeff | : | Not available. |
| Ionicity (in Water): | : | Not available. |
| Solubility | : | Easily soluble in methanol, acetone. Partially soluble in cold water, hot water. Soluble in Sulfuric Acid |
| Stability | : | The product is stable. |
| Instability Temperature | : | Not available |
| Conditions of Instability | : | Incompatible materials |
| Incompatibility with various substances | : | Highly reactive with organic materials, metals, acids. Reactive with reducing agents, combustible materials. |
| Corrosivity | : | Not available. |
| Special Remarks on Reactivity | : |
It is a powerful oxidizing agent. Incompatible with reducing agents, acids, formaldehyde, ammonium nitrate,dimethylformamide, glycerol, combustible materials, alcohols, arsenites, bromides, iodides, charcoal, organic substances, ferrous or mercurous salts, hypophosphites, hyposulfites, sulfites, peroxides, oxalates, ethylene glycol, Manganese salts in air oxidize the toxic sulfur dioxide to more toxic sulfur trioxide. Can react violently with most metal powders, ammonia, ammonium salts, phosphorous, many finely divided organic compounds (materials), flammable liquids, acids, sulfur. |
| Polymerization | : | Will not occur. |
|
Routes of Entry |
Absorbed through skin. Eye contact. Inhalation. Ingestion. |
|
Toxicity to Animals |
Acute oral toxicity (LD50): 1090 mg/kg [Rat]. Lowest Published Lethal Dose: LDL[Woman] - Route: Oral; Dose: 100 mg/kgLDL[Human] - Route: Oral; Dose: 143 mg/kg. |
|
Chronic Effects on Humans |
MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. May cause damage to the following organs: kidneys, liver, skin,central nervous system (CNS). |
|
Other Toxic Effects on Humans |
Hazardous in case of skin contact (irritant), of eye contact (corrosive), of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator). |
|
Special Remarks on Toxicity to Animals |
Not available. |
|
Special Remarks on Chronic Effects on Humans |
May cause adverse reproductive effects (Male and Female fertility) based on animal data. May affect genetic material (mutagenetic) based on animal data. |
|
Ecotoxicity |
Not available |
|
Mobility |
Completely soluble in water |
|
BOD5 and COD |
Not available |
|
Products of Biodegradation |
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. |
|
Special Remarks on the Products of Biodegradation |
Not available |
|
Disposal considerations |
Waste must be disposed of in accordance with federal, state and local environmental control regulations. |
- Not classified as hazardous for transport
- DOT Classification: CLASS 5.1: Oxidizing material.
- Identification: : Potassium permanganate UNNA: 1490 PG: II
- Special Provisions for Transport: Not available.
|
Federal and State Regulations |
Connecticut carcinogen reporting list.: Potassium permanganate Illinois toxic substances disclosure to employee act: Potassium permanganate Illinois chemical safety act: Potassium permanganate New York release reporting list: Potassium permanganate Rhode Island RTK hazardous substances: Potassium permanganate Pennsylvania RTK: Potassium permanganate Massachusetts RTK: Potassium permanganate Massachusetts spill list: Potassium permanganate New Jersey: Potassium permanganate New Jersey spill list: Potassium permanganate Louisiana spill reporting: Potassium permanganate California Director's list of Hazardous Substances: Potassium permanganate |
|
Other Regulations |
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. |
|
HMIS (U.S.A.): |
Health Hazard: 2 |
|
National Fire Protection Association |
Health: 1 |
| Protective Equipment: |
Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. |
|
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Rx Marine International be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |